Rosberg mencatatkan, 0.0059 s lebih pantas daripada Lewis Hamilton bagi membolehkan dua rakan sepasukan itu meraih kedudukan satu dua bagi perlumbaan esok.
Pelumba Red Bulls, Daniel Ricciardo dan Sebastian Vettel di tempat ketiga dan keempat.
Berikut adalah keputusan penuh sesi kelayakan yang berlangsung pada Sabtu:
FORMULA 1 GRAND PRIX DE MONACO 2014
| Pos | No | Driver | Team | Q1 | Q2 | Q3 | Laps |
|---|---|---|---|---|---|---|---|
| 1 | 6 | Nico Rosberg | Mercedes | 1:17.678 | 1:16.465 | 1:15.989 | 26 |
| 2 | 44 | Lewis Hamilton | Mercedes | 1:17.823 | 1:16.354 | 1:16.048 | 27 |
| 3 | 3 | Daniel Ricciardo | Red Bull Racing-Renault | 1:17.900 | 1:17.233 | 1:16.384 | 22 |
| 4 | 1 | Sebastian Vettel | Red Bull Racing-Renault | 1:18.383 | 1:17.074 | 1:16.547 | 25 |
| 5 | 14 | Fernando Alonso | Ferrari | 1:17.853 | 1:17.200 | 1:16.686 | 27 |
| 6 | 7 | Kimi Räikkönen | Ferrari | 1:17.902 | 1:17.398 | 1:17.389 | 27 |
| 7 | 25 | Jean-Eric Vergne | STR-Renault | 1:17.557 | 1:17.657 | 1:17.540 | 26 |
| 8 | 20 | Kevin Magnussen | McLaren-Mercedes | 1:17.978 | 1:17.609 | 1:17.555 | 25 |
| 9 | 26 | Daniil Kvyat | STR-Renault | 1:18.616 | 1:17.594 | 1:18.090 | 23 |
| 10 | 11 | Sergio Perez | Force India-Mercedes | 1:18.108 | 1:17.755 | 1:18.327 | 26 |
| 11 | 27 | Nico Hulkenberg | Force India-Mercedes | 1:18.432 | 1:17.846 | 20 | |
| 12 | 22 | Jenson Button | McLaren-Mercedes | 1:17.890 | 1:17.988 | 20 | |
| 13 | 77 | Valtteri Bottas | Williams-Mercedes | 1:18.407 | 1:18.082 | 20 | |
| 14 | 8 | Romain Grosjean | Lotus-Renault | 1:18.335 | 1:18.196 | 23 | |
| 15 | 13 | Pastor Maldonado | Lotus-Renault | 1:18.585 | 1:18.356 | 21 | |
| 16 | 19 | Felipe Massa | Williams-Mercedes | 1:18.209 | No time | 10 | |
| 17 | 21 | Esteban Gutierrez | Sauber-Ferrari | 1:18.741 | 11 | ||
| 18 | 99 | Adrian Sutil | Sauber-Ferrari | 1:18.745 | 11 | ||
| 19 | 17 | Jules Bianchi | Marussia-Ferrari | 1:19.332 | 10 | ||
| 20 | 4 | Max Chilton | Marussia-Ferrari | 1:19.928 | 9 | ||
| 21 | 10 | Kamui Kobayashi | Caterham-Renault | 1:20.133 | 9 | ||
| 22 | 9 | Marcus Ericsson | Caterham-Renault | 1:21.732 | 9 | ||
| Q1 107% Time | 1:22.985 |
